Henrikh Mkhitaryan scored to assist boss Paulo Fonseca that was new with a 4-2 triumph over Sassulo for his success.
As the visitors were put to the sword in the first half, the Armenia global, who joined the capital club on loan from Arsenal on transit day, scored his side’s third goal .
Roma were 4-0 up thanks to Bryan Cristantes header, a volley a written end and Mkhitaryan attack from Justin Kluivert.
The visitors came through Domenico Berardi’s double in the second half but it was too little too late.
The outcome moves Roma into seventh position about five points, four behind leaders Inter Milan, while Sassuolo are after taking three points in their opening three matches 12th.
Earlier in the afternoon, SPAL stunned European hopefuls Lazio since they came from behind to win 2-1 thanks to Jasmin Kurtic’s late winner.
Bologna went joint-second after pulling off a remarkable comeback in Brescia, recovering from a deficit to win 4-3 after Daniele Dessena was shipped off after the break shortly for the hosts.
While Cagliari won 3-1 away to Parma, duvan Zapata scored a stunning strike to earn a 2-1 victory at Genoa to Atalanta.
Go to the top of La Liga for the first time and joan Jordan’s goal was enough for Sevilla to win at Alaves this season.
Atletico Madrid’s 3-2 defeat at Real Sociedad on Saturday night ended Sevilla and the league’s just perfect album took good great advantage of this slide up with a success.
Jordan curled using 25 minutes to the clock at a free-kick that was brilliant as Sevilla passed up numerous opportunities to double their lead and it demonstrated at the Basque nation.
Stay mid-table and alaves failed to have a single shot on goal.
Elsewhere, Celta Vigo had Beltran and Saenz delivered off in the 29 moments in the home and suffered a 2-0 defeat on the newly-promoted side.
Califa Koulibaly’s aim was enough to move Nantes up to fourth with a 1-0 win over Stade Reims, that missed the opportunity remain and to move into the top half.
Elsewhere, Bournemouth winger Max Gradel along with ex-Leeds scored against his former club in Toulouse’s 2-2 draw Saint-Etienne, in which the hosts clawed back from a two-goal deficit.
David Wagner’s Schalke came out of succeed 5-1 at second-bottom Paderborn, a triumph which moved them up to sixth in the table together with seven points from four matches.
Before Salif Sane equalised at the 33rd with a header of his own, cauly headed encouraged Paderborn in front in the eighth minute.
Suat Serder’s deflected shot gave the lead four minutes set up with on-loan Everton full-back Jonjoe Kenny made it 3-1 at the 71st minute.
Substitute Ahmed Kutucu and Harit netted as Schalke respectively in the minutes wrapped up.
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